What is the conjugate base in the following reaction? HNO₂ + H₂O ⇌ ?
-
A
OH⁻
-
B
NO₂⁻
-
C
H₃O⁺
-
D
HNO₃
The conjugate base in the reaction is NO₂⁻.
According to the Brønsted-Lowry acid-base theory, an acid is a proton (H⁺) donor, and a base is a proton acceptor. The conjugate base is the species formed when an acid donates a proton.
A) OH⁻
Hydroxide ion is the conjugate base of water acting as an acid (H₂O → H⁺ + OH⁻). However, in this reaction, water is acting as a base by accepting a proton from HNO₂. Therefore, the conjugate acid of H₂O is H₃O⁺, not OH⁻. OH⁻ is not directly formed from HNO₂ losing a proton.
B) NO₂⁻
In the forward reaction, nitrous acid (HNO₂) acts as the acid, donating a proton (H⁺) to water. The species remaining after HNO₂ loses a proton is the nitrite ion, NO₂⁻. By definition, NO₂⁻ is the conjugate base of the acid HNO₂.
C) H₃O⁺
Hydronium ion (H₃O⁺) is formed when water, acting as a base, accepts a proton (H⁺). Therefore, H₃O⁺ is the conjugate acid of the base H₂O. It is not a conjugate base in this reaction pair.
D) HNO₃
Nitric acid (HNO₃) is a different, stronger acid. It is not formed in this reaction by simply adding or removing a proton from HNO₂. The conjugate base must differ from its acid by exactly one proton (H⁺). HNO₃ has the same number of protons as HNO₂ and is a different molecular species altogether.
Conclusion:
The conjugate base is always derived from its corresponding acid by the removal of one proton (H⁺). In the reaction HNO₂ + H₂O ⇌ H₃O⁺ + NO₂⁻, the acid HNO₂ loses a proton to become NO₂⁻, making NO₂⁻ its conjugate base.

Topic Flashcards
Click to FlipAccording to Brønsted-Lowry theory, what is the definition of a conjugate base?
The species formed when an acid donates a proton (H⁺). It is the original acid molecule minus one H⁺.
In the reaction HNO₂ + H₂O ⇌ H₃O⁺ + NO₂⁻, which species acts as the Brønsted-Lowry acid and which acts as the base on the reactant side?
HNO₂ is the acid (donates H⁺). H₂O is the base (accepts H⁺).
For the acid HNO₂, what is its conjugate base, and how is it related structurally?
The conjugate base is NO₂⁻ (nitrite ion). It is the species formed when HNO₂ loses one H⁺.
What is the conjugate acid of the base H₂O in this reaction, and what is its name?
The conjugate acid is H₃O⁺, called the hydronium ion.
In the reverse reaction (H₃O⁺ + NO₂⁻ ⇌ HNO₂ + H₂O), what is the conjugate base of H₃O⁺?
H₂O. In the reverse direction, H₃O⁺ acts as an acid, donating H⁺ to become H₂O, its conjugate base.