If sodium sulfide (Na₂S) and hydrochloric acid (HCl) react in a double-replacement reaction, what product(s) form?
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A
Na₂SHCl
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B
NaHCl + S
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C
NaCl + H₂S
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D
HCl + Na₂S
The products of this double-replacement reaction are sodium chloride (NaCl) and hydrogen sulfide gas (H₂S).
In a double-replacement (metathesis) reaction, the positive ions (cations) of two ionic compounds exchange partners. The general form is AB + CD → AD + CB. For the reaction between sodium sulfide (Na₂S) and hydrochloric acid (HCl), the Na⁺ and H⁺ ions exchange places. Sodium pairs with chloride to form sodium chloride, a soluble salt. Hydrogen pairs with sulfide to form hydrogen sulfide (H₂S). Hydrogen sulfide is a gas with a characteristic rotten egg odor. Its formation as a product that bubbles out of the solution is one of the driving forces that makes this reaction proceed to completion.
A) Na₂SHCl
This suggests the reactants simply combined into one molecule without an exchange of ions. This is not a recognized type of reaction for ionic compounds in aqueous solution and does not represent the pattern of double-replacement.
B) NaHCl + S
The formula "NaHCl" does not represent a stable ionic compound. Sodium and hydrogen do not form a simple binary salt like this; hydrogen typically acts as a cation only in acids. Elemental sulfur (S) is also not a typical product. In sulfide (S²⁻) reactions, sulfur usually remains as part of an anion or forms a gaseous compound like H₂S, not elemental sulfur.
C) NaCl + H₂S
This is correct. The ions exchange: Na⁺ from Na₂S combines with Cl⁻ from HCl to form NaCl. H⁺ from HCl combines with S²⁻ from Na₂S to form H₂S. The balanced molecular equation is: Na₂S(aq) + 2HCl(aq) → 2NaCl(aq) + H₂S(g).
D) HCl + Na₂S
This is simply a list of the reactants, indicating no chemical reaction occurred. In a double-replacement reaction, new compounds must form as products.
Conclusion:
Double-replacement reactions often proceed when one of the products is a precipitate, a gas, or a molecular compound like water. The reaction between sodium sulfide and hydrochloric acid is a classic example where gas formation (H₂S) drives the reaction. The correct products are the soluble salt sodium chloride and hydrogen sulfide gas.

Topic Flashcards
Click to FlipIn a double-replacement reaction, the positive ions (cations) of two compounds do what?
They exchange places (swap partners) with each other.
What are the two products when sodium sulfide (Na₂S) reacts with hydrochloric acid (HCl)?
Sodium chloride (NaCl) and hydrogen sulfide gas (H₂S).
In the reaction Na₂S + 2HCl → 2NaCl + H₂S, what is the state (e.g., solid, aqueous, gas) of the product H₂S, and why is that important?
H₂S is a gas (g). Its formation removes a product from the solution, which helps drive the reaction to completion.
Balance the double-replacement reaction: Na₂S + HCl → NaCl + H₂S
Na₂S (aq) + 2HCl (aq) → 2NaCl (aq) + H₂S (g)
What is the general form of a double-replacement reaction, using the letters A, B, C, and D to represent ions?
AB + CD → AD + CB