100% 4 Rated
Attempts 127

Why does fluorine have a higher ionization energy than oxygen?

  1. A
    Smaller neutron number
  2. B
    . Larger neutron number
  3. C
    Smaller nuclear charge
  4. D
    Larger nuclear charge

Topic Flashcards

Click to Flip
Question

Define ionization energy. What trend does it follow across a period (left to right) on the periodic table, and what is the primary reason?

Answer

Ionization energy is the energy required to remove an electron from a gaseous atom. It generally increases across a period due to increasing nuclear charge, which pulls electrons closer more strongly.

Question

Why is there a slight dip in the ionization energy trend between Nitrogen (N) and Oxygen (O), even though the general trend is increasing?

Answer

Oxygen's electron configuration has two paired electrons in one 2p orbital, which experience electron-electron repulsion, making one slightly easier to remove than nitrogen's more stable half-filled 2p subshell.

Question

What two opposing factors—related to nuclear attraction and electron-electron repulsion—determine the ease of removing an electron?

Answer

1) Effective Nuclear Charge: The net positive charge felt by an electron (stronger pull = harder to remove). 2) Shielding/Repulsion: Inner electrons shield outer electrons from the nucleus, and electron-electron repulsion in the same orbital can make an electron easier to remove.

Question

Predict which element in Period 2 (from Li to Ne) has the highest first ionization energy and explain your reasoning.

Answer

Neon (Ne). It has the largest effective nuclear charge in Period 2, pulling its electrons in very tightly. Additionally, its electron configuration (a stable, filled octet) is very difficult to disturb.

Question

Between Magnesium (Mg) and Aluminum (Al), which has a lower first ionization energy? Explain why this exception to the trend occurs.

Answer

Aluminum has a lower first ionization energy. The electron removed from Al is in a higher-energy 3p orbital, which is farther from the nucleus and shielded by the 3s electrons, making it easier to remove than an electron from Mg's filled and stable 3s orbital.

Mini Quiz

1 / 3
Does ionization energy always decrease as you move down a group on the periodic table?
Available Test Sets
Available FREE Test Sets